Estimation of the proton affinity values of fifteen matrix-assisted laser desorption/ionization matrices under electrospray ionization conditions using the kinetic method. J Am Soc Mass Spectrom 2004 Mar;15(3):431-5
Date
03/05/2004Pubmed ID
14998547DOI
10.1016/j.jasms.2003.12.001Scopus ID
2-s2.0-1442284500 (requires institutional sign-in at Scopus site) 61 CitationsAbstract
The kinetic method, which is known to be simple, fast and precise, is used for the measurement of proton affinity values of fifteen selected matrix-assisted laser desorption/ionization matrices under electrospray ionization conditions. The stabilization of [M - H](-)/[M + Matrix - H](-) ions for beta-cyclodextrin in negative ion mode has been rationalized based on the proton affinity values of the matrices.









