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Chemical switching behaviour of tricarbonylrhenium(I) complexes of a new redox active 'pincer' ligand. Dalton Trans 2010 Apr 07;39(13):3167-9

Date

05/08/2010

Pubmed ID

20449442

DOI

10.1039/c001344g

Scopus ID

2-s2.0-77949512424 (requires institutional sign-in at Scopus site)   34 Citations

Abstract

The structures and optoelectronic properties of tricarbonylrhenium(I) complexes of di(2-pyrazolyl-p-tolyl)amine in its neutral and deprotonated (uninegative amido) form were investigated. Reactions of the complexes with Brønsted acids or bases result in distinctive changes of colour and electrochemical activity owing to the non-innocent nature of the ligand.

Author List

Wanniarachchi S, Liddle BJ, Toussaint J, Lindeman SV, Bennett B, Gardinier JR

Author

Brian Bennett D.Phil. Professor and Chair in the Physics department at Marquette University




MESH terms used to index this publication - Major topics in bold

Amines
Coordination Complexes
Ligands
Oxidation-Reduction
Rhenium
Spectrophotometry, Ultraviolet