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Chae Yi PhD
Professor, Inorganic and Organometallic Chemistry, Homogeneous Catalysis
Institution:
Marquette University
Department:
Chemistry
Member of the Cancer Center
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Publications (23)
Scope and Mechanistic Analysis for Chemoselective Hydrogenolysis of Carbonyl Compounds Catalyzed by a Cationic Ruthenium Hydride Complex with a Tunable Phenol Ligand.
(Kalutharage N, Yi CS)
J Am Chem Soc
2015 Sep 02;137(34):11105-14 PMID: 26235841 08/04/2015
32 Citations
Synthesis of 2-Acylphenol and Flavene Derivatives from the Ruthenium-Catalyzed Oxidative C-H Acylation of Phenols with Aldehydes.
(Lee H, Yi CS)
European J Org Chem
2015 Mar;2015(9):1899-1904 PMID: 26167129 PMCID: PMC4493914 07/15/2015
Chemoselective formation of unsymmetrically substituted ethers from catalytic reductive coupling of aldehydes and ketones with alcohols in aqueous solution.
(Kalutharage N, Yi CS)
Org Lett
2015 Apr 03;17(7):1778-81 PMID: 25803313 PMCID: PMC6585420 03/25/2015
17 Citations
Deaminative and decarboxylative catalytic alkylation of amino acids with ketones.
(Kalutharage N, Yi CS)
Angew Chem Int Ed Engl
2013 Dec 16;52(51):13651-5 PMID: 24174407 11/01/2013
18 Citations
Dehydrative C-H alkylation and alkenylation of phenols with alcohols: expedient synthesis for substituted phenols and benzofurans.
(Lee DH, Kwon KH, Yi CS)
J Am Chem Soc
2012 May 02;134(17):7325-8 PMID: 22494241 04/13/2012
Scope and Mechanistic Study of the Coupling Reaction of α, β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling Pathways.
(Kwon KH, Lee DW, Yi CS)
Organometallics
2012 Jan 09;31(1):495-504 PMID: 22368318 PMCID: PMC3285248 03/01/2012
Selective catalytic C-H alkylation of alkenes with alcohols.
(Lee DH, Kwon KH, Yi CS)
Science
2011 Sep 16;333(6049):1613-6 PMID: 21921195 09/17/2011
Chelate-Assisted Oxidative Coupling Reaction of Arylamides and Unactivated Alkenes: Mechanistic Evidence for Vinyl C-H Bond Activation Promoted by an Electrophilic Ruthenium-Hydride Catalyst.
(Kwon KH, Lee DW, Yi CS)
Organometallics
2010 Oct 21;29(22):5748-5750 PMID: 21344062 PMCID: PMC3041965 02/24/2011
Tetrasubstituted olefins through the stereoselective catalytic intermolecular conjugate addition of simple alkenes to α,β-unsaturated carbonyl compounds.
(Kwon KH, Lee DW, Yi CS)
Angew Chem Int Ed Engl
2011 Feb 11;50(7):1692-5 PMID: 21308934 PMCID: PMC3869203 02/11/2011
20 Citations
Recent advances in the synthetic and mechanistic aspects of the ruthenium-catalyzed carbon-heteroatom bond forming reactions of alkenes and alkynes.
(Yi CS)
J Organomet Chem
2011 Jan 01;696(1):76-80 PMID: 21278832 PMCID: PMC3026479 02/01/2011
Chain- and Regioselective Ethylene and Styrene Dimerization Reactions Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: New Insights on the Styrene Dimerization Mechanism.
(Lee DW, Yi CS)
Organometallics
2010 Jan 01;29(15):3413-3417 PMID: 20694188 PMCID: PMC2915581 08/10/2010
Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation.
(Yi CS, Lee DW)
Organometallics
2010 Mar 19;29(8):1883-1885 PMID: 20567607 PMCID: PMC2887707 06/23/2010
Regioselective formation of alpha-vinylpyrroles from the ruthenium-catalyzed coupling reaction of pyrroles and terminal alkynes involving C-H bond activation.
(Gao R, Yi CS)
J Org Chem
2010 May 07;75(9):3144-6 PMID: 20384382 PMCID: PMC2865850 04/14/2010
31 Citations
Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an In-Situ Formed Cationic Ruthenium-Hydride Complex.
(Yi CS, Lee DW)
Organometallics
2009 Aug 10;28(15):4266-4268 PMID: 20161548 PMCID: PMC2805103 02/18/2010
Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids.
(Yi CS, Gao R)
Organometallics
2009 Oct 30;28(22):6585-6592 PMID: 20161379 PMCID: PMC2782529 02/18/2010
Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-mu-Oxo-mu-Hydroxo-Hydride Complex.
(Yi CS, Lee DW)
Organometallics
2009 Jan 29;28(4):947-949 PMID: 20119477 PMCID: PMC2658527 02/02/2010
Aqueous phase C-H bond oxidation reaction of arylalkanes catalyzed by a water-soluble cationic Ru(III) complex [(pymox-Me2)2RuCl2]+BF4-.
(Yi CS, Kwon KH, Lee DW)
Org Lett
2009 Apr 02;11(7):1567-9 PMID: 19245262 PMCID: PMC2667693 02/28/2009
79 Citations
Highly Cooperative Tetrametallic Ruthenium-mu-Oxo-mu-Hydroxo Catalyst for the Alcohol Oxidation Reaction.
(Yi CS, Zeczycki TN, Guzei IA)
Organometallics
2006;25(4):1047-1051 PMID: 18726005 PMCID: PMC2519863 08/30/2008
Formation of bicyclic pyrroles from the catalytic coupling reaction of 2,5-disubstituted pyrroles with terminal alkynes, involving the activation of multiple C-H bonds.
(Yi CS, Zhang J)
Chem Commun (Camb)
2008 May 28(20):2349-51 PMID: 18473066 PMCID: PMC3876409 05/14/2008
10 Citations
Scope and mechanistic study of the ruthenium-catalyzed ortho-C-H bond activation and cyclization reactions of arylamines with terminal alkynes.
(Yi CS, Yun SY)
J Am Chem Soc
2005 Dec 07;127(48):17000-6 PMID: 16316246 PMCID: PMC2585980 12/01/2005
130 Citations
Ruthenium-catalyzed intermolecular coupling reactions of arylamines with ethylene and 1,3-dienes: mechanistic insight on hydroamination vs ortho-C-H bond activation.
(Yi CS, Yun SY)
Org Lett
2005 May 26;7(11):2181-3 PMID: 15901164 05/20/2005
72 Citations
Catalytic synthesis of tricyclic quinoline derivatives from the regioselective hydroamination and C-H bond activation reaction of benzocyclic amines and alkynes.
(Yi CS, Yun SY, Guzei IA)
J Am Chem Soc
2005 Apr 27;127(16):5782-3 PMID: 15839664 04/21/2005
104 Citations
Regio- and stereoselective ruthenium-catalyzed hydrovinylation of 1,3-dienes: application to the generation of a 20(S) steroidal side chain.
(He Z, Yi CS, Donaldson WA)
Org Lett
2003 May 01;5(9):1567-9 PMID: 12713325 04/26/2003
45 Citations